Regioselective Hydrocarbamoylation of 1-Alkenes
نویسندگان
چکیده
منابع مشابه
Acid-free regioselective aminocarbonylation of alkenes.
An efficient method for the synthesis of N-aryl monosubstituted carboxamides via the Pd-catalyzed carbonylation of alkenes with CO and amines is described. Mechanistic insights for this highly selective reaction are provided.
متن کاملAn iron catalyzed regioselective oxidation of terminal alkenes to aldehydes.
Fe(BF(4))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid and PhIO can efficiently catalyze the regioselective oxidation of terminal alkene derivatives to aldehydes under mild and benign reaction conditions.
متن کاملPotassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes.
The regio- and diastereoselective silaboration of aromatic alkenes with a silylboron compound proceeds in the presence of a catalytic amount of potassium tert-butoxide, providing a complementary method to the corresponding transition metal-catalyzed reactions.
متن کاملEnantio- and regioselective CuH-catalyzed hydroamination of alkenes.
A highly enantio- and regioselective copper-catalyzed hydroamination reaction of alkenes has been developed using diethoxymethylsilane and esters of hydroxylamines. The process tolerates a wide variety of substituted styrenes, including trans-, cis-, and β,β-disubstituted styrenes, to yield α-branched amines. In addition, aliphatic alkenes coupled to generate exclusively the anti-Markovnikov hy...
متن کاملRegioselective palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes.
A novel Pd-catalyzed regioselective intramolecular aminofluorination of unactivated alkenes has been developed, which is an efficient method for the synthesis of a variety of monofluoromethylated nitrogen-containing heterocycles.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemistry Letters
سال: 2012
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.2012.298